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Oriental Motor
Technical Article

Approach to Lead-Free Soldering for Electric Circuit

Masanori Amemiya

1. Introduction
Oriental Motor Co., Ltd. launched the lead-free solder project in November of 1999 in response to the Restriction of Hazardous Substances in Electrical and Electronic Equipment (RoHS Directive) that will be enforced in the EU starting July 01, 2006.
The melting point of the Sn-Ag-Cu lead-free solder system is about 220°C, which is about 40°C higher than that of Sn-Pb eutectic solder (melting point 183°C) that is currently being used, meaning that it cannot be used in the current manufacturing process. Using Sn-Ag-Cu lead-free solder requires more heat resistant parts and a reflow furnace with high-accuracy temperature control.

Oriental Motor implemented a new circuit board manufacturing system that included equipment that could control the temperature accurately enough for the lead free solder reflow process and redesigned our control circuits to incorporate electronic parts that were rated for the required higher temperatures. These changes were implemented in December of 2005. This paper will discuss the activities undertaken by Oriental Motor to switch to a lead-free solder system.

2. Definition and category of a lead-free solder system
The lead-free solder system project goal was to achieve Phase 3 based on the “Definition and category of lead-free” from the lead-free solder’s practical use roadmap 2002 (1) of JEITA (Japan Electronics and Information Technology Industries Association).

Definition of lead-free:
The amount of lead contained in a prescribed part to be considered lead-free is assumed to be less than 0.1 % by weight.

Category of lead-free:

Phase 1: Lead-free solder equipment A
At the board mounting stage, lead solder is not used for the PWB (Printed Wire Board) surface finish, solder print, and solder bath, etc. Lead may be contained in the wiring terminals of the parts, inside the parts, and constituent material, etc.

Phase 2: Lead-free solder equipment B
At the board mounting stage, lead solder is not used for PWB surface finish, solder print, and solder bath, and lead is not contained in the wiring terminals of the parts to be mounted. Lead may be contained inside of the parts, and constituent material.

Phase 3: Lead-free solder equipment
In addition to the definition of lead-free solder equipment, lead is not contained in constituent components and/or materials.

3. Lead-free system of control circuit
In a control circuit, places where lead is used includes the PWB surface finish, solder for connection (solder print and solder bath (tank)), external terminals of the electronic parts, and solder for internal connections of the electronic parts. Fig. 1 shows where solder is commonly used in the control circuit.

Figure 1

Fig. 1 Places where solder is used

3.1. PWB surface finish
The PWB surface finish was changed from a lead solder leveler to a heatproof preflux or lead-free leveler.

3.2. Solder for connection
As for the solder used for connecting the parts to the PWB, the solder material was changed to meet manufacturing process.

3.2.1. Flow process: Solder bath (tank)
The stick solder used for the flow process was changed from Sn3 7Pb to Sn3Ag0.5Cu.

3.2.2. Reflow process: Solder print
The cream solder used for the reflow process was changed from Sn37Pb to Sn3Ag0.5Cu.

3.3. Mounting parts
By working with each of our electronic part manufacturers and suppliers, we were able to switch to lead-free parts as related to the plating of the terminals, the internal solder connections of the electronic parts, and their constituent materials.

4. Selection of materials
The method used to select the solder materials and the PWB surface finish materials used in the process as follows.

4.1. Solder materials
For the cream solder and the stick solder, etc., an industry standard, high-reliability Sn3Ag0.5Cu solder recommended by JEITA was selected.

4.2. PWB surface finish material
A switch from lead solder to preflux was made. For the selection, the following items were evaluated based on the data from each preflux maker.

4.2.1. Solderability
There must be sufficient solder flow up into the through-hole after two reflow passes on the test PWB (FR-4, 1.6mm thick, through-hole diameter 0.8mm, pad diameter 1.35mm).

4.2.2. Migration test (Note 1)
The deterioration of the preflux doesn't generate any migration, and it satisfies with the insulation resistance test based on the JIS Z3284 Solder paste Appendix 14 Migration test.
(Test condition: 85°C at 85% rh, leaving in a tank at constant temperature and humidity, applied voltage DC50V, and 2,000 hours)

5. Joint Reliability
Table 1 shows the evaluation items for joint reliability.
This section will describe the migration test, soldering strength test based on the thermal, mechanical reliability, and the electrochemical reliability.

5.1. Soldering strength test
As a typical example, the shear load of a solder joint was measured before and after a heat cycle test of the PC board with size 2120 chip parts mounted. The joint reliability was confirmed to be equivalent to Sn37Pb solder.

Table 1 Joint Reliability Evaluation Items




Thermal・Mechanical reliability

Static fracture

Thermal fatigue fracture

Creep fracture

Vibration fracture

Impact fracture

Electro chemical reliability


Ion migration

Electro migration



Sn Whisker(Note2)

Corrosion Fatigue fracture

Inter metallic compound

Table 2 shows the test conditions, and Fig. 2 shows the shear load test of the 2120 size chip parts.

Table 2 Soldering strength test




Test PWB( FR-4, Thickness:1.6mm)


–40~125°C30min 500cycle


Test methods for lead-free solder -- Part 7: Methods for shear strength of solder joints on chip components

Figure 2

Fig. 2 Shear load of 2120 size chip parts

5.2. Migration test
It is confirmed that it doesn't generate the migration, and is satisfied with the insulation resistance by evaluating based on the data of makers of cream solder materials. Table 3 sows the test conditions.

Table 3 Migration test


(PWB FR-4, Thickness 1.6mm)


85°C85% rh、Thermostatic constant humidity chamber.
Input voltageDC45V、1000hr.


JIS Z 3284 Solder paste Annex14 Migration test.

Figure 3

Fig. 3 Temperature profile of reflow furnace

(Note 1) Migration is a phenomenon that occurs when a metal or a metallic compound separates out between patterns of a printed circuit board. When an electric field is applied between electrodes while water in the form of moisture absorption or condensation is present, dissolution and a deposition reaction can occur. This is an electrochemical phenomenon that can cause the metal to grow from the cathode toward the anode.

(Note 2) A whisker is the needle shaped crystal (single crystal in a needle shape) generated from the metals such as Sn and Zn. According to the characteristic of the metal, a distortion arises in the crystal structure when a stress is applied, and the metal changes into an undistorted, larger crystal (recrystallization of the metal) when the distorted crystal reaches a certain temperature (recrystallization temperature). The needle crystal that extends from the metal surface is called a whisker.

6.1 Reflow process
Since the melting point of Sn3Ag0.5Cu solder is higher than standard solder, it is necessary to raise the reflow temperature nearly to the temperature rating of the electronic parts. For this reason, a more accurate temperature control system is required. Therefore, a reflow furnace that can control the temperature more accurately was selected for use. For the temperature control profile, a trapezoidal profile was selected based on the size of the parts and the thermal capacity of the PC board. Fig. 3 shows the basic temperature profile used by Oriental Motor.

6.2. Flow process
As for lead getting mixed in into the solder bath, this was reduced by using lead-free PCB surface finishes and lead-free electronic parts. However, impurities in the solder bath are checked regularly to ensure that the content of lead is less than 0.1 % by weight.

7. Electronic parts
The plating on the terminals of the electrical parts was evaluated based on the data supplied by the electronic parts manufacturers. The actual plating was evaluated for solder wettability, solder strength, and whiskers (Note 2) with four terminal plating types: Sn, Sn-Ag, Sn-Bi, and Sn-Cu when used in combination with Sn3Ag0.5Cu solder.

7.1. Test of solder wettability
Sufficient solder wettability was confirmed by measuring the time when the wetting starts (zero-crossing time) with 1608 size chip parts by the rapid heating method. Table 4 shows the test conditions.

Table 4 Test of solder wettability




Soldering temperature:Sn3Ag0.5Cu 250°C
Sn37Pb    230°C

7.2. Soldering strength test
The shear strength of the solder joint was tested before and after the heat cycle test on a PC board with the size 1608 chip parts mounted. The joint reliability was confirmed to be equivalent to Sn37Pb solder. Table 5 shows the test conditions.

Table 5 Soldering length test




–55~125°C 30min 1000cycle


Test methods for lead-free solders -- Part 7: Methods for shear strength of solder joints on chip components

7.3. Whisker test
The whiskers that are generated at the joint of the FFC (flexible flat cable) and the connector were evaluated. After leaving the joint at room temperature, the connector was broken down and examined for the generation of whiskers at each contact by SEM (scanning electron microscopy). The resistance to generation of whisker was determined to satisfactory. Table 6 shows the test conditions.

Table 6 Whisker test


Connector:Sn Plating、Pitch 1.25mm
FFC  :Sn Plating
(Whisker resistance spec.)


Leaving as joined at room temperature for 2000hr

8. Summary
The transition to a lead-free solder system for control circuits made it necessary for all of the conventional manufacturing processes to be reviewed.
The problems encountered for each step of the process were resolved, the reliability was evaluated, and a lead-free solder mass production system was achieved. Finally, it would have been even more difficult to achieve our goal for a lead-free solder system without the considerable cooperation from our parts suppliers and the new materials that are available.

(1) JEITA Committee drafting the Roadmap of lead-free solder in practical use: Roadmap of lead-free solder in practical use 2002 Ver.2.1 Japan Electronics and Information Technology Industries Association (2002)

Masanori AMEMIYA

Masanori Amemiya

Circuit Technology Center

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